IRON OXIDE is a ferric oxide-based additive (Fe₂O₃) used for daily hydrogen sulphide (H₂S) control in biogas plants. Hydrogen sulphide is a common biogas contaminant that can corrode equipment and reduce the quality of the biogas; IRON OXIDE helps tackle this problem directly inside the digester. This fine powder additive is introduced regularly to the fermenter, where it reacts with dissolved sulphides and H₂S, thus lowering the H₂S content in the biogas. By doing so, it protects the downstream equipment (like gas engines or scrubbers) and helps maintain a healthy microbial environment (excess H₂S can inhibit certain microbes). IRON OXIDE is especially recommended for installations that consistently need to reduce biogas H₂S levels and require additional iron to stabilise their biological process.
Reduces H₂S in Biogas: IRON OXIDE directly lowers the hydrogen sulphide concentration in the biogas, resulting in cleaner gas that often requires less scrubbing or cleaning downstream. This helps meet H₂S emission limits and protects engines from corrosive gas.
Prevents Biological Inhibition: By releasing iron into the fermenter, it prevents H₂S-related inhibition of the digestion process. Hydrogen sulphide in solution can be toxic to microbes; binding it with iron forms insoluble iron sulphide, reducing toxicity and odour.
Enhances Process Stability: Iron is an essential micronutrient for certain anaerobic bacteria. IRON OXIDE provides a source of iron that can help stabilise the biological process in the digester, especially if the feedstock is low in trace nutrients.
Operational Cost Savings: With less H₂S in the biogas, you’ll experience lower maintenance costs – engine oil lasts longer, gas filters and scrubbers have a lighter load, and you avoid corrosion damage. It can reduce the frequency of activated carbon replacements or chemical scrubbing, saving money.
Simple Daily Use: The product is applied as part of the daily routine, making it a straightforward solution to implement. It can be added along with feedstock, requiring minimal extra labour or changes to your process.
IRON OXIDE’s mode of action relies on the chemical reaction between iron oxide and hydrogen sulphide. When the fine powder is added to the digester, it disperses in the slurry. The ferric oxide (Fe₂O₃) reacts with dissolved sulfide ions (S⁻²) and H₂S gas present in the digestate, resulting in the formation of iron sulfides (such as FeS or Fe₂S₃). This reaction effectively locks up the sulphur in a solid form that remains in the digestate instead of releasing as H₂S gas. As a result, the biogas that bubbles out of the digester has a lower concentration of H₂S.
Additionally, the iron from IRON OXIDE serves a dual purpose: once it reacts, the iron is still in the system (as iron sulphide or other forms) and can be utilised by microorganisms or help precipitate other impurities (like phosphate). The continuous supply of iron can improve the nutritive balance of the digester if iron was a limiting element. Microbially, certain anaerobes that process sulphur compounds (like sulphate-reducing bacteria) will produce H₂S as a byproduct; having readily available iron means that H₂S is immediately captured, thereby reducing its inhibitory effect on methanogens. In summary, IRON OXIDE works by chemically scavenging hydrogen sulphide and fortifying the digester with iron, leading to cleaner biogas and a more stable environment for methane-producing microbes.
IRON OXIDE is intended for daily use. It is typically added into the digester feed system or mixing tank so that it disperses well:
Solid Feeding System: If your plant has a solid feeder (like a conveyor or hopper for substrates), you can sprinkle or dose the daily amount of IRON OXIDE powder onto the feedstock each day.
Premix/Slurry Tank: If there’s a premix tank, add the powder to this tank. It can be added directly or mixed with some process water first to help distribution.
Direct to Digester: In some cases, operators may blow or flush the powder directly into the fermenter.
The recommended dosage is to include IRON OXIDE in every daily feed cycle at a rate consistent with your H₂S levels. A general guidance from Realistic Agri is to dose each day via the solid loading system or premix tank. The exact amount will depend on the size of the plant and the H₂S challenge:
Smaller plants (e.g., farm-scale 100 kW systems) might start with a few hundred grams per day.
Larger plants (e.g., 1 MW) might dose multiple kilograms per day.
The dose can be adjusted based on biogas H₂S measurements – the goal is to find the amount that keeps H₂S consistently low without over-supplying iron.
It’s often beneficial to consult with a Realistic Agri representative to determine the starting dose. They might perform an analysis or use prior experience with similar feedstocks to recommend a quantity (for instance, “X kg per 100 m³ of digester volume per day”). It’s also important to distribute the dose well (don’t clump it in one spot) for effective H₂S capture..
IRON OXIDE is provided as a very fine powder (to maximise its surface area and reactivity). It typically comes in 25 kg biodegradable paper bags, arranged on 1100 kg pallets for bulk delivery. The biodegradable bags mean you can potentially add them whole if they are designed to dissolve, but often with fine powders, you might open the bag and scoop/apply as needed.
Storage: Keep the bags in a dry location to prevent clumping or premature reaction (the powder can absorb moisture from air). The powder is stable under normal conditions, but storing it off the ground and covered will maintain its quality. Avoid areas with extreme humidity or where the bags could tear.
Handling: As a fine powder, IRON OXIDE can be dusty. It’s advisable to wear a dust mask or respirator, gloves, and goggles when handling it to avoid inhalation or eye contact. The powder is not toxic, but inhaling any fine particulate isn’t healthy. Use dedicated scoops or feeders to handle the product. If it comes in soluble bags, handling is simpler – just move the bags and drop them in as needed (gloves are still good to have, as the bags can have powder residue). Be aware that iron oxide powder is a rusty brown color; it can stain skin or clothing and make a mess if spilled, so handle it carefully. Any spills should be swept up and can be added to the digester or disposed of as benign waste (since it’s essentially an iron compound found in nature).
Controlling H₂S with IRON OXIDE can yield substantial cost savings and protect your revenue streams:
Engine and Equipment Protection: Lower H₂S means less corrosion in gensets, gas boilers, and piping. This prolongs the life of engines and reduces the frequency of oil changes and overhauls. A well-protected CHP engine can save tens of thousands in maintenance over its lifetime. Those savings contribute directly to ROI by avoiding downtime and replacement costs.
Reduced Gas Cleaning: In instances where activated carbon or chemical scrubbers are used for H₂S removal, adding IRON OXIDE in the digester can lighten the load on those systems. Carbon filters will last longer before saturation, and chemical usage (like ferrous chloriaustic for scrubbers) can be reduced. Lower consumable usage translates to monthly operational cost savings.
Compliance and Biogas Utilisation: High H₂S can sometimes force flaring of biogas or reduced generator output to stay within emission limits. Using IRON OXIDE helps you fully utilise your biogas for energy without curtailment, maximising your income from FITs or RHI (incentives). Compliance fines or environmental fees are also mitigated.
Process Yield: While the primary role is H₂S scrubbing, you may also benefit from slightly enhanced biomethanation if iron was a limiting nutrient. More stable digestion (with no sulphide toxicity) can increase methane yield a bit, which adds to revenue.
Minimal Investment & Easy Implementation: The cost of IRON OXIDE additive is relatively low compared to major equipment. Its implementation is simple (no new machinery needed), so the payback is often immediate as soon as it starts reducing other expenses. When you consider the value of protecting a multimillion-pound biogas plant and ensuring continuous power generation, the peace of mind gains alone can justify the investment.
In essence, IRON OXIDE helps to safeguard your biogas plant’s performance and assets, which is a smart investment for any operator aiming for long-term profitable operation.
IRON HYDROXIDE is a ferric hydroxide-based additive (FeO(OH)) formulated to combat hydrogen sulphide in biogas, with a focus on fast-acting H₂S control. It can be used in daily H₂S management, similar to iron oxide, but is particularly effective when you need to quickly address spikes of H₂S in the biogas. When your digester experiences sudden surges in H₂S levels – perhaps due to a transient feedstock issue or a disturbance – IRON HYDROXIDE reacts swiftly to sequester the sulphur. This helps maintain safe H₂S concentrations and prevents those spikes from causing harm to the biogas utilisation equipment or the microbial process. Additionally, like other iron additives, it contributes iron to the digester, aiding in overall biological stability. IRON HYDROXIDE is recommended for AD installations that periodically face high H₂S challenges and require a robust solution to keep levels in check.
Fast Reaction to H₂S Spikes: IRON HYDROXIDE has a high reactivity, allowing it to quickly capture sudden increases in hydrogen sulphde. This makes it ideal as a “shock treatment” when H₂S levels threaten to rise beyond normal.
Continuous Sulphur Control: Beyond just emergencies, it serves as a reliable daily H₂S control additive. Regular use lowers overall H₂S content in biogas, reducing the need for extensive gas scrubbing downstream.
Prevents Process Inhibition: By binding H₂S, the additive prevents the inhibitory effects of sulphide on your digester’s microbes. A well-buffered sulphide level means methanogens and other bacteria can operate without sulphide toxicity, keeping methane production robust.
Augments Iron Levels: IRON HYDROXIDE adds bioavailable iron into the fermenter, which can help stabilise the digestion process if your feedstock is low in iron. Iron is important for enzyme systems and can enhance breakdown of certain compounds.
Equipment Protection: With effective sulphur removal at the source, your CHP engines, boilers, and gas pipelines see less corrosion and wear, prolonging their life and reducing maintenance costs (similar benefit as iron oxide, just often even more needed when spikes occur).
Iron hydroxide operates on a similar principle to iron oxide – by chemically reacting with hydrogen sulphide. The active substance, ferric hydroxide [FeO(OH)], when introduced into the anaerobic digester, will encounter sulfide (S²⁻) and hydrogen sulfide (H₂S) present in the slurry. In effect, IRON HYDROXIDE converts H₂S gas into solid iron sulphide precipitate. This precipitate stays mixed with the digestate and eventually exits with it, thus removing H₂S from the biogas phase.
Ferric hydroxide is often considered slightly more reactive or faster-acting in wet conditions compared to ferric oxide, due to its hydroxide form which can be more readily soluble. This means IRON HYDROXIDE can begin scavenging sulphides very quickly after dosing, which is why it’s favored for spike control. The presence of iron hydroxide can also co-precipitate other contaminants and provide trace iron to microbes. The net effect is a rapid drop in H₂S gas levels after application, and maintenance of those low levels with continuous use.
From a biological standpoint, by removing H₂S, IRON HYDROXIDE alleviates stress on methane-forming microbes that can occur if H₂S accumulates. This ensures the fermentation process continues smoothly even during what would have been a “sour” event. In summary, the mode of action is chemical neutralisation of sulphide, working swiftly to guard both the process and the equipment from sulphur’s harmful effects.
IRON HYDROXIDE can be used in two modes:
Preventative Daily Dosing: Similar to iron oxide, you might add IRON HYDROXIDE every day as part of your routine to keep baseline H₂S levels low.
Curative Spike Dosing: Kept on hand to add quickly when you detect a rising H₂S trend (for instance, if a monitoring sensor shows an upward spike or if high-sulphur feedstock was added).
In practice, many operators will incorporate a small daily dose and have the flexibility to increase the dose if needed. The product is a powder that can be added via:
Solid feed hopper: Mix the iron hydroxide powder with your substrates or drop the soluble bag in.
Liquid recirculation line: Sometimes, powders can be mixed with a bit of water and added through a recirculation pump or injector to spread it quickly.
Top feeding port: Dumping the powder directly into the top of the digester (if accessible) for rapid distribution.
Dosage guidelines: IRON HYDROXIDE is typically added in quantities similar to iron oxide. It can be added daily into the solid loading system or premix tank, with or without water-soluble packaging. Specific amounts will depend on your H₂S levels:
For ongoing use, an approximate starting point might be on the order of 0.5–1 kg per 100 m³ of digester volume per day (this is a rough estimate; for a 1,000 m³ digester that might be 5–10 kg/day).
To combat a spike, you might temporarily double or triple the daily dose until H₂S is under control.
Always consult the product guidance or a Realistic Agri specialist to tailor the dose. They may recommend doing a sulphide test on your digestate to know how much free sulphide is present and dose accordingly. Since IRON HYDROXIDE comes in 20 kg bags on 1000 kg pallets, you might measure out a portion of a bag each day. If using water-soluble bags, each bag could be sized for a certain daily dose (e.g., a 500 g or 1 kg soluble packet per feeding for smaller plants).
When handling dosing, try to distribute the powder or packets across the feeding period (if you feed multiple times a day, split the dose accordingly) so that the iron is always present to catch H₂S as it’s produced.
IRON HYDROXIDE is provided as a powder, typically packaged in 20 kg biodegradable paper bags, with large orders delivered as 1000 kg (1 tonne) pallets of those bags. The bags are water-soluble, which allows adding the whole bag without opening it.
Storage: Keep the bags palletised in a dry storage area. The material should not get wet before use, as moisture will cause it to clump or react prematurely. It’s best stored similarly to iron oxide – off the ground, covered, and away from direct moisture.
Handling: Wear appropriate PPE such as dust mask, gloves, and eye protection when handling the powder. Ferric hydroxide can be a yellow-brown color and is fine like talcum; it will create dust if not handled gently. If using water-soluble bags, the handling is easier – just avoid puncturing the bags. During application, ensure any mixing equipment (if used to pre-mix with water) is corrosion-resistant (plastic or stainless) since iron compounds can be a bit abrasive. Clean any equipment or surfaces that come into contact with the powder to avoid staining or lingering dust.
Because IRON HYDROXIDE may be used sporadically for spikes, make sure partially used bags are sealed tightly to avoid absorbing moisture from the air. The product is stable, so leftover material from a spike event can be stored for future use as long as it’s kept dry.
IRON HYDROXIDE can be viewed as both an insurance policy and a performance enhancer for your biogas plant:
Damage Prevention (Insurance): By suppressing H₂S spikes, it prevents sudden damage or shutdowns. A single H₂S surge that goes unchecked could cause a costly failure (for instance, damaging an engine’s exhaust system or causing a sulphuric acid corrosion issue). Using IRON HYDROXIDE avoids these catastrophic costs, which by itself may pay for the product many times over.
Maintaining Power Output: H₂S spikes can force operators to temporarily throttle down CHP engines or flare gas to avoid damage. With effective control, you keep generating power at full capacity, securing your revenue. In this way, IRON HYDROXIDE indirectly secures your income stream by ensuring gas quality remains within usable range.
Reduced Consumable Costs: Facilities often treat biogas H₂S either in-situ or ex-situ. If you rely on external gas scrubbing (like iron sponge, carbon, or liquid scrubbers), using IRON HYDROXIDE in-situ can reduce the frequency of media change-outs or chemical use. This saves on purchasing those consumables and the labour to maintain them.
Microbial Health = Efficiency: By keeping the microbial inhibitors at bay, your digester can run at optimum health, meaning more biogas per feedstock input. Over time, that higher efficiency (even if a few percent) accumulates into more kWh produced. Essentially, you’re ensuring that a potential efficiency loss due to sulphide stress is averted – a subtle but important ROI factor.
Versatility and Longevity: Unused IRON HYDROXIDE doesn’t go bad quickly – if your plant’s H₂S is under control, the product can sit until needed. This means your investment is not wasted; you have a tool ready for when a problem arises. Think of it as having a fire extinguisher in the control room: inexpensive relative to the asset it protects, and invaluable when needed.
In financial terms, the cost of daily iron hydroxide dosing is typically minor compared to the gains of prolonged engine life, consistent output, and fewer operational hiccups.
METHO-FILTER is an innovative biogas filtration medium designed as an alternative to traditional activated carbon filters for removing hydrogen sulphide and other impurities from biogas. It consists of specially formulated iron hydroxide pellets (Fe(OH)₃) that physically and chemically scrub H₂S out of the gas stream. These pellets are used to fill a filter vessel through which raw biogas passes before reaching your engine or upgrading equipment.
The key advantage of METHO-FILTER over regular activated carbon is its higher H₂S capacity and the fact that spent pellets can be reused within the biogas plant (for example, added into the digester), eliminating costly disposal of used media.
By using METHO-FILTER, biogas plant operators can extend the life of their CHP engines, reduce oil change frequency, and cut down on the recurring expense of purchasing and disposing of activated carbon.
High H₂S Removal Capacity: METHO-FILTER has a greater hydrogen sulphide filtering capacity than standard activated carbon filters. This means it can treat more biogas (or higher H₂S concentrations) before it becomes saturated, resulting in longer intervals between media changes.
No Disposal Costs: Unlike spent activated carbon (which often must be treated as special waste), spent METHO-FILTER pellets can be utilised in the biogas plant itself. For instance, once the pellets are spent, you can add them into the digester; the iron sulphide within them can break down and integrate into the digestate. This eliminates disposal costs and adds value back to the system.
Protects Engines and Equipment: By effectively removing H₂S and possibly other contaminants, METHO-FILTER prevents damage to CHP engines, generators, and boilers. This protection can result in significantly longer service life for engine components and exhaust systems, and it can extend the oil change intervals because the oil is not getting contaminated by sulphur acids.
Cost-Effective Operation: Although the initial media might be an investment, the extended life and reuse aspects make METHO-FILTER very cost-effective. You’ll spend less frequently on replacements and avoid fees for hazardous waste removal. Over time, this can be cheaper than constantly replacing activated carbon, particularly for plants with high H₂S levels.
Operational Flexibility: METHO-FILTER pellets come in different sizes (small and large) to be layered for optimal filtration. This gives flexibility in filter design and can minimise pressure drop while maximising contact with the gas. They can be used in existing carbon vessels (with some modifications) or new filter units designed for pellet media.
METHO-FILTER works through a combination of adsorption and chemical reaction. The filter is filled with iron hydroxide pellets, which have a high surface area and are chemically reactive with hydrogen sulphide:
As biogas flows through the bed of pellets, H₂S in the gas is adsorbed onto the pellet surfaces.
The iron hydroxide in the pellets reacts with H₂S to form iron sulphides (similar to how iron oxide/hydroxide powders react in a digester) – effectively binding the sulphur onto the pellet in solid form.
The result is that H₂S is removed from the gas, and the gas exiting the filter has a much lower H₂S concentration, making it safe for engines or gas upgrading.
Because these pellets can hold a lot of sulphur, their lifespan in operation is longer. When they do eventually become saturated with sulphur (i.e., mostly converted to iron sulphide), the media is considered “spent.”
However, instead of having to throw it away, those iron sulphide pellets can be added back into your anaerobic digester. Inside the digester, two things can happen:
(1) The iron sulphide remains as part of the digestate (essentially adding micronutrients like iron back to the system),
or (2) some sulphide might be released and immediately consumed by the ongoing digestion chemistry (which likely has fresh iron to capture it). In any case, it closes the loop for sulphur management and reduces waste.
Additionally, by removing H₂S more effectively, METHO-FILTER ensures that corrosive hydrogen sulphide doesn’t make it to the engine. This is why engines see less corrosion and oils don’t acidify as quickly – the filter is stopping those harmful compounds upstream. A secondary effect is that because you can layer large and small pellets (large ones at the base for support and flow distribution, small ones on top for fine filtration), the pressure drop across the filter can be kept moderate while still achieving high filtration efficiency. The large pellets (5–25 mm) create channels and prevent clogging, while the smaller pellets (2–8 mm) provide a dense bed for thorough H₂S capture.
Application: METHO-FILTER is used in a gas filtration vessel – typically a vertical or horizontal tank through which biogas is flowed (after it leaves the digester and before it reaches the engine or gas upgrader). To implement METHO-FILTER:
Fill the vessel: Pour in a layer of large pellets (5–25 mm) to form the base (about 20–30% of the vessel volume). These larger pellets ensure good gas distribution and support.
Top up with small pellets (2–8 mm) to fill the remaining ~70–80% of the vessel. These smaller pellets have higher surface area for H₂S capture.
Make sure the vessel is properly sealed and the gas flow is set to pass uniformly through the pellet bed. It may be useful to have flow distributors or screens to keep pellets in place.
Commissioning: Slowly introduce biogas flow and monitor the outlet H₂S. Initially, the filter will remove a large fraction of H₂S. If the outlet is near zero H₂S, you may increase flow or wait until some saturation occurs.
There isn’t a “dosage” per se like liquid additives – rather, you size the filter and amount of media based on your gas production and H₂S content. For example, if you produce 500 m³/hour of biogas with 2000 ppm H₂S, you’ll need enough pellet volume to handle that load for a given time. Realistic Agri or Methodo will provide guidance on how many kg of pellets per m³ of gas or per ppm of H₂S.
Usage & Maintenance: Check the H₂S levels after the filter regularly. When you notice H₂S slip (i.e., the H₂S level after the filter begins to rise indicating media saturation), it’s time to replace or regenerate media:
Replace/Recycle: Take the spent pellets out. They can be shovelled or vacuumed out of the vessel. Then refill the vessel with fresh pellets in the same layering as before. The spent ones can be carefully added into the digester (perhaps gradually over several days to avoid overwhelming the system with sulphide).
Interval: The interval between media changes could be several months to over a year, depending on the H₂S load and filter size. This is much longer than many activated carbon change intervals.
Safety note: Always depressurise and ventilate the filter vessel before opening it to remove pellets. The spent pellets might have absorbed not just suphur but also moisture and possibly CO₂; handle them with gloves (iron sulphide can generate a bit of odour or even slight heat if exposed to air, though typically it's safe). When adding to the digester, do so during feeding times to mix them in.
Compatibility: METHO-FILTER pellets can often be used in the same canisters that held activated carbon, with minimal modification (maybe adding a screen if pellet size is smaller than the carbon granules to prevent carry-over).
METHO-FILTER pellets are shipped in bulk containers:
Small pellets (2–8 mm size) are usually in big bags (~550 kg) or drums, since you often need a larger volume.
Large pellets (5–25 mm size) are often in 25 kg bags, which are easier to handle when layering the bottom of the vessel.
Upon receiving them, store the pellet bags in a dry area. The pellets can absorb moisture from the air (since iron hydroxide is somewhat hydrophilic), and you don’t want them to react or clump before use. Keep them in their original packaging until you’re ready to fill the filter.
When handling the pellets:
Personal Protective Equipment: Wear gloves (to avoid any possible irritation or just dirt on hands) and a dust mask. While pellets produce far less dust than powder, some fine particles may be present in the bags, especially with the small pellet size.
Pouring/Loading: The big bags might require a forklift or hoist to position over the vessel and a chute to pour. The 25 kg bags can be manually lifted and dumped. Take care to pour slowly to avoid dust clouds. If possible, avoid windy days or do it indoors.
Spent Media Handling: When removing spent pellets, again wear appropriate PPE. The pellets might smell of sulphur. They are not hazardous waste, but standard precautions for handling used filter media apply (use tools to avoid direct contact, ventilate area).
Disposal/Recycle: If you choose not to put spent media into the digester, it can typically be disposed of as solid waste or potentially used as a soil amendment if regulations allow (it’s basically iron with sulfur). But the beauty of METHO-FILTER is you don’t have to pay for special disposal, as you can recycle it into the AD system.
METHO-FILTER can significantly improve the economics of gas cleaning:
Lower Media Costs Over Time: While high-quality activated carbon is expensive and must be replaced frequently, METHO-FILTER’s longer life and reusability mean you buy media less often and essentially get more H₂S removal per pound of media purchased. Over a year, many plants find the cost of using METHO-FILTER is lower than the cost of the multiple carbon refills they would have needed.
Elimination of Disposal Fees: Spent carbon often requires special handling and disposal (sometimes even classified as hazardous if sulphur content is high). These fees add up. With METHO-FILTER, disposal costs drop to near zero because the media is not wasted – it’s fed to the digester as an iron source. This not only saves money but also aligns with sustainability (waste-to-value principle).
Engine Maintenance Savings: By providing extremely clean gas to your engines, you save on maintenance. Oil changes can be extended (some operators see significantly less frequent oil acidification), and engine overhauls can be postponed because components wear out slower. These maintenance savings can be quite large, improving the ROI of the system. One noted benefit is that METHO-FILTER can extend the oil change interval of the co-generator, which directly reduces oil and labour costs.
Avoided Downtime: Media changes for carbon can be a messy, time-consuming job often requiring contractors. If METHO-FILTER allows longer intervals and quicker change-outs, you have less downtime or derating of your plant. Every hour your engine runs at full power instead of being down for maintenance is income earned rather than lost.
Improved Biogas Yield (Indirect): When you recycle the spent media into the digester, the sulphur captured eventually ends up in the digestate rather than vented or combusted. In some cases, this can slightly improve the overall sulphur balance of your process (for instance, you might be able to tolerate a bit more protein in feedstock because you have a strong sulphur removal mechanism). More importantly, the iron added back could help with nutrient balance. These subtle process improvements might increase biogas yield or stability, which again contributes positively to your bottom line.
In conclusion, METHO-FILTER provides a smart economic advantage by turning a typically consumptive process (gas scrubbing with one-time-use media) into a more circular, cost-saving system. The investment in the filter media and possibly a dedicated vessel is paid back through ongoing savings in media replacement, disposal, and engine longevity – crucial factors for any biogas plant’s profitability.